Preparation, Structural Study, Theoretical Treatment and Biological Activity of Cr (III), Ni (II), Cd (II) and V (IV) Complexes of Tetradentate Ligand Bis [4-Phenyl-3 (2- Propenyl) Thio-1, 2, 4-Triazole-5yl] Methane

Authors

  • Mahasin F Alias Department of Chemistry, College of Science for Women, University of Baghdad, Baghdad-Iraq.
  • Manal O Hamza Department of Chemistry, College of Science for Women, University of Baghdad, Baghdad-Iraq.
  • Tamara A Kareem Department of Chemistry, College of Science for Women, University of Baghdad, Baghdad-Iraq.

Keywords:

NON

Abstract

Some transition metal complexes Cr (III), Ni (II), Cd (II) and V (IV) Complexes of olefinic bistriazole as a ligand have been synthesized and characterized. The prepared complexes were identified and their structural geometries were suggested by using Flame Atomic Absorption technique, FT-IR and Uv-Visible Spectrophotometer as well as to Magnetic Susceptibility and Conductivity measurement. Semi-empirical methods (PM3 and MINDO/3) were carried out to evaluate the vibration frequencies, heat of formation (∆Hºƒ) and binding energy (ΔEb) for all metal complexes. And it is also studying their biological activity against two selected microorganisms (pseudomonas aeruginosa and staphylococcus aureus).

Published

2011-06-01

Issue

Section

Articles

How to Cite

(1)
Preparation, Structural Study, Theoretical Treatment and Biological Activity of Cr (III), Ni (II), Cd (II) and V (IV) Complexes of Tetradentate Ligand Bis [4-Phenyl-3 (2- Propenyl) Thio-1, 2, 4-Triazole-5yl] Methane. ANJS 2011, 14 (2).