Synthesis of New Isoxazolin - Phenoxathiin Derivatives

Authors

  • Ayad Ahmed Mohamad Department of Research and Quality Control, Daura Refinery, Ministry of Oil.
  • Suad M AL-Araji Department of Chemistry, College of Science, University of Baghdad, Baghdad-Iraq.

Keywords:

Phenoxathiin, Oxoalken derivatives, Hydroxylamine, Isoxazoline

Abstract

The aim of the present work is synthesis of new phenoxathiin derivatives. The 2-(oxoalken-1-yl) phenoxathiin derivatives (3a-3j) obtained from the reaction 2-acetylphenoxathiin with different aromatic aldehyde in the presence of sodium hydroxide. The reaction of 2-(oxoalken-1-yl) phenoxathiin derivatives (3a-3j) with hydroxylamine hydrochloride in ethanolic sodium hydroxide solution to get 2-(isoxazolin-3-yl) phenoxathiin derivatives (4a-4j) which substituted at position (5) in isoxazoline ring with different aryl groups according to aromatic aldehyde used in the preparation of (3a-3j). All the synthesized compounds were characterized by different identification techniques to confirm structure which has been obtained.

Published

2018-07-03

Issue

Section

Articles

How to Cite

[1]
“Synthesis of New Isoxazolin - Phenoxathiin Derivatives”, ANJS, vol. 17, no. 1, pp. 50–60, Jul. 2018, Accessed: Mar. 28, 2024. [Online]. Available: https://anjs.edu.iq/index.php/anjs/article/view/479