Synthesis, Characterization and Theoretical Study of Some Mixed-ligand Complexes of 2-Quinoline Carboxylic Acid and 4,4⁄ -dimethyl,2,2⁄-Bipyridyl with Some Transition Metal Ions

Authors

  • Mahasin Alias Department of Chemistry, College of Science for Women, University of Baghdad, Baghdad-Iraq.
  • Sahar Ismael Department of Chemistry, College of Science for Women, University of Baghdad, Baghdad-Iraq.
  • Souad Abd Mousa Department of Chemistry, College of Science for Women, University of Baghdad.

Keywords:

Quinoline-2-Carboxylic Acid, 4,4⁄ -dimethyl,2,2⁄ -Bipyridyl, Hyperchem.8,spectroscopy, Theoretical treatment, Gaussian program

Abstract

New mixed ligand complexes have been prepared by the reaction of Quinoline- 2-Carboxylic Acid (HL1) and 4,4⁄ -dimethyl,2,2⁄ -Bipyridyl (L2) with Co(II),Ni(II) u(II), Zn(II), Pd(II) and Au(III) ions. The newly prepared complexes were isolated and characterized by (FT-IR) and (UVVis) spectroscopy, elemental analysis, flame tomic absorption technique, thermo gravimetric analysis, in addition to magnetic susceptibility and conductivity measurements. A theoretical treatment of these ligands and prepared complexes in gas phase were studied using Hyper chem.8 program, moreover, ligands in gas phase also have been studied using Gaussian program (GaussView Currently Available Versions (5.0.9) along with Gaussian 09 which is the latest in the Gaussian series of programs).

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Published

2018-06-14

Issue

Vol. 18 No. 1 (2015): March

Section

Articles

How to Cite

[1]
“Synthesis, Characterization and Theoretical Study of Some Mixed-ligand Complexes of 2-Quinoline Carboxylic Acid and 4,4⁄ -dimethyl,2,2⁄-Bipyridyl with Some Transition Metal Ions”, ANJS, vol. 18, no. 1, pp. 28–38, Jun. 2018, Accessed: Apr. 18, 2024. [Online]. Available: https://anjs.edu.iq/index.php/anjs/article/view/346