Photo-responsive evaluation of solution-processed self-driven visible-blind NiO/ZnO/FTO photodetector

Authors

  • Mohammed Ali H. Al-Beayaty Department of Renewable Energy, College of Energy and Environmental Sciences, Al-Karkh University of Science, Baghdad, Iraq.
  • Abdal Kareem A. Dhahir University of Information Technology and Communication, Baghdad, Iraq.
  • Maryam Abdulghafor Ahmed Department of Renewable Energy, College of Energy and Environmental Sciences, Al-Karkh University of Science, Baghdad, Iraq.

Keywords:

Photodetector, NiO/ZnO/FTO, Solution-processed, Self-driven, Visible-blind

Abstract

In this article, the fabrication procedure of solution-processed NiO/ZnO/FTO heterostructure is systematically elucidated for self-driven visible-blind photodetector application. In detail, the opto-electrical analysis was investigated under multi-illumination wavelength of 375 nm, through which a linear dependency between the photocurrent ( ) and the incident intensity was perceived along a close to unity Pearson correlation coefficient ( ). The proposed heterojunction (p-NiO/n-ZnO) exhibited short-circuit current and open-circuit voltage of 4 µA and 0.8 V, which in turn validates the self-powered feature of the proposed geometry. The attained photo-responsivity ( ) and photo-detectivity ( ) exhibited values of 25.6 mA/W and 16.3  Jones, respectively, under light intensity of 17 mW/cm2. This was noticed along with considerable ( ) reduction near the visible light region. In conjunction, p-NiO/n-ZnO heterostructure demonstrated UV/vis rejection ratio ( ) of 572; other considered geometries (NiO/FTO and ZnO/FTO) revealed considerably lower ratios. At zero bias, the addressed junction demonstrated response/recovery times of 0.175 and 0.178 sec., respectively.

References

[1] Aldaghri, O.; Salih, E.Y.; Ramizy, A., Mohammed, A.S.; Ibnaouf, K.H.; Eisa, M.H.; "Rapid fabrication of fast response CdS/Si visible light photodetector: Influence of laser energy". Results in Physics, 54: 107112, 2023.

[2] Ahmed, D.S.; Mohammed, M.K.; "Novel mixed solution of ethanol/MACl for improving the crystallinity of air-processed triple cation perovskite solar cells". Solar Energy, 207: 1240-6, 2020.

[3] Salim, E.T.; Fakhri, M.A.; Tariq, S.M.; Azzahrani, A.S.; Ibrahim, R.K.; Alwahib, A.A.; et al. "The unclad single-mode fiber-optic sensor simulation for localized surface plasmon resonance sensing based on silver nanoparticles embedded coating". Plasmonics, 19: 131-43, 2024.

[4] Ghlem, M.A.H.; Ahmed, M.A.; Dhahir, A.K.A.; Al-Khafaji, T.K.M.S.; Thamer, S.A.; "Room temperature NO2 gas sensor based mesoporous Zn/Al-layered double hydroxide". The effect of molar ratio. Materials Letters, 376: 137280, 2024.

[5] Al-Taa'y, W.A.; Al-Beayaty, MA.H.; Abbas, L.J.; "Microstructural and Mechanical Properties Study of Al/SiC composite prepared by PM technique". Iraqi Journal of Science, 459-68, 2025.

[6] Ahmed, D.S.; Mohammed, M.R.; Mohammed, M.K.; "Synthesis of multi-walled carbon nanotubes decorated with ZnO/Ag nanoparticles by co-precipitation method". Nanoscience & Nanotechnology-Asia, 10:127-33, 2020.

[7] Mohammed, M.K.; "Studying the structural, morphological, optical, and electrical properties of CdS/PbS thin films for photovoltaic applications". Plasmonics, 15:1989-96, 2020.

[8] Bashir, M.B.A.; Salih, E.Y.; Rajpar, A.H.; Bahmanrokh, G.; Sabri, M.F.M.; "The impact of laser energy on the photoresponsive characteristics of CdO/Si visible light photodetector". Journal of Micromechanics and Microengineering, 32: 085006, 2022.

[9] Al-Beayaty,M.A.H.; Abbas, L.K.; "Mohammed RK. Effect of L-cysteine capping the CdSe, CdSe: CdS on structural and morphological properties". AIP Conference Proceedings: AIP Publishing, 2023.

[10] Salih, E.Y.; "Fabrication and photodetection performance evaluation of nanostructured CdS/Si MSM visible light photodetector". Optical Materials, 149:115120, 2024.

[11] Salih, E.; Ramiz, y.A.; Aldaghr, i.O.; Eisa, M.H.; Ibnaouf, K.H.; "Solution processed self-powered broadband flower-like Zn (Al) O-mixed metal oxide dye sensitized photodetector". Materials Letters, 362:136213, 2024.

[12] Abdulghani, S.O.; Salih, E.Y.; Mohammed, A.S.; "Fabrication and photo-responsive characteristics of GeO2 doped SnO2/porous Si film for ultraviolet photodetector application". Materials Chemistry and Physics, 303:127859, 2023.

[13] Mohammed, A.S.; Fahad, O.A.; Ramizy, A.; Salih, E.Y.; "Thickness effect of Al2O3 as buffer layer on Alq3 sensitivity for toxic gas". Ceramics International, 47:17907-14, 2021.

[14] Salleh, F.; Usop, R.; Saugi, N.S.; Salih, E.Y.; Mohamad, M.; Ikeda, H.; et al. "Influence of TiO2 layer's nanostructure on its thermoelectric power factor". Applied Surface Science, 497:143736, 2019.

[15] Klochko, N.; Kopach, V.; Tyukhov, I.; Zhadan, D.; Klepikova, K.; Khrypunov, G.; et al. "Metal oxide heterojunction (NiO/ZnO) prepared by low temperature solution growth for UV-photodetector and semi-transparent solar cell. Solar Energy". 164:149-59,2018.

[16] Al-Beayaty, M.A.H.; "Structural, optical and morphological characterization of Cdse/Cds Core/shell quantum dots synthesized via chemical bath". Iraqi Journal of Science, 4323-32, 2021.

[17] Debnath, R.; Xie, T.; Wen, B.; Li, W.; Ha, JY.; Sullivan, NF.; et al. "A solution-processed high-efficiency p-NiO/n-ZnO heterojunction photodetector". Rsc Advances, 5:14646-52, 2015.

[18] Bashir, M.B.A.; Said, S.M.; Sabri, M.F.M.; Miyazaki, Y.; Shnawah, D.A.; Shimada, M,; et al. "In-filled La 0.5 Co 4 Sb 12 skutterudite system with high thermoelectric figure of meri"t. Journal of Electronic Materials, 47:2429-38, 2018.

[19] Salih, E.Y.; Sabri, M.F.M.; Sulaiman, K.; Hussein, M.Z.; Said, S.M.; Usop, R.; et al. "Thermal, structural, textural and optical properties of ZnO/ZnAl2O4 mixed metal oxide-based Zn/Al layered double hydroxide". Materials Research Express, 5:116202, 2018.

[20] Salih, E.Y.; Ramizy, A.; Aldaghri, O.; Mohd Sabri, M.F.; Madkhali, N.; Alinad, T.; et al. "In-depth optical analysis of Zn (Al) O mixed metal oxide film-based Zn/Al-layered double hydroxide for TCO application". Crystals, 12:79, 2022.

[21] Salih, E.Y.; Abbas, Z.; Al Ali, S.H.H.; Hussein M.Z.; "Dielectric behaviour of Zn/Al-NO 3 LDHs filled with polyvinyl chloride composite at low microwave frequencies". Advances in Materials Science and Engineering, 2014, 2014.

[22] Mohammad, M.R.; Ahmed, D.S.; Mohammed, M.K.; "ZnO/Ag nanoparticle-decorated single-walled carbon nanotubes (SWCNTs) and their propertie". Surface Review and Letters, 27:1950123, 2020.

[23] Salih, E.Y.; Bashir, M.B.A.; Rajpar, A.H.; Badruddin, I.A.; Bahmanrokh, G.; "Rapid fabrication of NiO/porous Si film for ultra-violate photodetector: The effect of laser energy". Microelectronic Engineering, 258:111758, 2022.

[24] Patel, M.; Kim, J.; "Transparent NiO/ZnO heterojunction for ultra-performing zero-bias ultraviolet photodetector on plastic substrate". Journal of Alloys and Compounds, 729:796-801, 2017.

[25] Mohammed,Salam,A.;Hasan, Ali.; Al-Taa'y, Wasan.A.; Ahmed, Ahmed.; Khalaf, Maji.; ; Yousif, Emad.;," Optical properties Study of New Films Derived from poly(vinyl chloride)- N-(4-Hydroxy-phenyl)-acetamide". Research Journal of Pharmaceutical, Biological and Chemical Sciences, 7( Issue 4) :1064 - 1071, 2016.

[26] Dinesh, V.P.; Biji, P.; Kumaravel, M.; Tyagi, A.; Kamaruddin, M.; "Synthesis and characterization of hybrid ZnO@ Ag core-shell nanospheres for gas sensor applications". Materials Science Forum: Trans Tech Pub, 768-73, 2012.

[27] Nalage, S.; Navale, S.; Patil, V.; "Polypyrrole-NiO hybrid nanocomposite: structural, morphological, optical and electrical transport studies". Measurement, 46:3268-75, 2013.

[28] Al-Taa'y, Wasan.A.; Hasan, Bushra. A.;" Design and Fabrication of Nanostructure TiO2 Doped NiO as A Gas Sensor for NO2 Detection". Iraqi Journal of Science, 62 (Issue 11): 4385 - 439625, 2021

[29] Drozdowska, K.; Welearegay, T.; Österlund, L.; Smulko, J.; "Combined chemoresistive and in situ FTIR spectroscopy study of nanoporous NiO films for light-activated nitrogen dioxide and acetone gas sensing". Sensors and Actuators B: Chemical, 353:131125, 2022.

[30] Vivek, C.; Balraj, B.; Thangavel, S.; "Structural, optical and electrical behavior of ZnO@ Ag core–shell nanocomposite synthesized via novel plasmon-green mediated approach". Journal of Materials Science: Materials in Electronics, 30:11220-30, 2019.

[31] Mohammed, M.K.; Al-Mousoi, A.K.; Khalaf, H.A.;. "Deposition of multi-layer graphene (MLG) film on glass slide by flame synthesis technique". Optik,127:9848-52, 2016.

[32] Bashir, M.B.A.; Salih, E.Y.; Sabri, M.F.M.; "Rajpar AH, Badruddin IA, Hussein MZ, et al. In-depth thermal, microstructural and photoluminescence analysis of mesoporous ZnO/ZnAl2O4-MMO: the effect of molar ratio". ECS Journal of Solid State Science and Technology, 10:106006 ,2021.

[33] Mohammed M.K.; Naji, A.M.; Ahmed, D.S.; Jamai, M.J.; Salih, E.Y,; Dehghanipour, M.; et al. "Facile synthesis of chitosan-MoS2 over reduced graphene oxide to improve photocatalytic degradation of methylene blu"e. Journal of Sol-Gel Science and Technology,1-11, 2024.

[34] Salih, E.Y.; "Characterization and performance evaluation of nanostructured rod-like CdTe/Si fast-response visible light photodetector". Physica B: Condensed Matter, 685:416056, 2024.

[35] Salih, E.;"Opto-electrical evaluation of visible blind fast-response nanostructured SnO 2/Si photodetector". RSC advances., 14:27733-40, 2024.

[36] Huang, Z.; Zhou ,Y.; Luo, Z.; Yang, Y.; Yang, M.; Gao, W.; et al. "Integration of photovoltaic and photogating effects in a WSe 2/WS 2/p-Si dual junction photodetector featuring high-sensitivity and fast-response". Nanoscale Advances, 5:675-84, 2023.

[37] Ghosh, C.; Dey, A.; Biswas, I.; Gupta, R.K.; Yadav, V.S.; Yadav, A.; et al. "CuO–TiO2 based self-powered broad band photodetector". Nano Materials Science, 6:345-54, 2024.

[38] Salih, E.Y.; "Fabrication of CdSe/Si nanostructure for self-powered visible light photodetector". Materials Letters, 371:136930, 2024.

[39] Yu, S.H.; Lee, Y.; Jang, S.K.; Kang, J.; Jeon, J,.; Lee, C.; et al. "Dye-sensitized MoS2 photodetector with enhanced spectral photoresponse". ACS nano, 8:8285-91, 2014.

[40] Lee,Y.;Yu, S.H.; Jeon,J.; Kim, H.; Lee,.J.Y.; Kim,H.;et al. "Hybrid structures of organic dye and graphene for ultrahigh gain photodetectors". carbon. 88:165-72, 2015.

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Published

2025-09-15

Issue

Section

Mathematics

How to Cite

(1)
Ali H. Al-Beayaty, M. .; A. Dhahir, A. K. .; Abdulghafor Ahmed, M. . Photo-Responsive Evaluation of Solution-Processed Self-Driven Visible-Blind NiO ZnO FTO Photodetector. Al-Nahrain J. Sci. 2025, 28 (3), 111-118.